Lutetium(III) oxide

Lutetium(III) oxide
Identifiers
CAS number 12032-20-1 Y
Properties
Molecular formula Lu2O3
Molar mass 397.932 g/mol
Melting point

2490 °C

Boiling point

3980 °C

Solubility in other solvents moderate
Structure
Molecular shape N/A
Dipole moment N/A<
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Lutetium(III) oxide, a white solid, is a cubic compound of lutetium sometimes used in the preparation of specialty glasses. It is also called lutecia. It is a lanthanide oxide, also known as a rare earth.[1]

History

In 1879, Jean-Charles-Galissard de Margnac (1817-1894), a French chemist, claimed to have discovered ytterbium, but actually he had found a mixture of elements. In 1907, a French chemist Georges Urbain (1872-1938) reported that ytterbium was a mixture of two new elements and not a single element. Two more chemists came to the same conclusion. They were from Germany, Karl Auer (1858-1929) and America, Charles James (1880-1926). The two compounds they discovered were neoytterbium and lutecium. However, none of these chemists actually dealt with pure lutetium. The compound they found was usually lutetium oxide.[2]

Uses

The product of Lu2O3 and PdO (formed at high pressure and temperature in the presence of potassium chlorate) has a potential use in superconducting materials.[3] Lutetium(III) oxide is an important raw material for laser crystals. It also has specialized uses in ceramics, glass, phosphors, and lasers. Lutetium(III) Oxide is used as a catalyst in cracking, alkylation, hydrogenation, and polymerization.[1]

References

  1. ^ a b Lutetium Oxide. 1997-2007. Metall Rare Earth Limited.<http://www.metall.com.cn/luo.htm?gclid=CKrqtNDdyIsCFR0CPwodEkZnHw>
  2. ^ Lutetium. 2005-2006. Bookrags.<http://www.bookrags.com/research/lutetium/>
  3. ^ Lutetium (III) oxide. 2007. Sigma Aldrich.<http://www.sigmaaldrich.com/catalog/search/ProductDetail/ALDRICH/289191>